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Journal of Cellular Plastics
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Blends of CO2 and 2-Ethyl Hexanol as Replacement Foaming Agents for Extruded Polystyrene

Louis E. Daigneault

National Research Council of Canada, 75 de Mortagne Blvd, Boucherville, Quebec, Canada J4B 6Y4; IPEX Inc., Product Development Engineering, Port of Montreal Building, Wing 3, 1st Floor, Cité du Havre, Montreal, Quebec, Canada H3C 3R5.

Richard Gendron

National Research Council of Canada 75 de Mortagne Blvd. Boucherville, Quebec, Canada J4B 6Y4

By the year 2010, HCFC 142b will be banned for use as a foaming agent for extruded polystyrene (PS) foam in North America. Many blends of foaming agents have been patented as replacements to expand PS. In this study the optimal concentration of a previously unexplored blend of CO2 and 2-ethyl hexanol (2-EH) is shown to allow the production of PS foam of 30 kg/m3 density. The glass transition temperature reduction of the PS, due to the incorporation of 2-EH, is believed to be an important contributor to the success of this foaming agent blend. In long-term use of the foams, the 2-EH does not measurably diffuse out of the PS, whereas the half-life of CO2 diffusion out of the foam is measured in weeks.

Journal of Cellular Plastics, Vol. 37, No. 3, 262-272 (2001)
DOI: 10.1106/TTWV-JAXU-C40R-02EA


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